XSplit VCam can be used on either Skype for Desktop, the pre-installed version of Skype in Windows 10 (from the Microsoft Store) and Skype for Business. Here are the steps to do it:

On Skype, click beside your name on Skype then select Settings.

Settings Menu highlighted in Skype

On the Settings window, click Audio & Video.

Audio & Video selected in Skype's Settings

Select XSplit VCam from the Camera drop-down menu.

Selecting XSplit VCam as the camera in Skype's video settings
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